VMware vCenter Server
Fewer than two ESXi hosts in the cluster have access to the target datastore.
Only datastores that shared by more than one host in the vSphere HA cluster will appear in the list of heartbeat datastores.
To use the datastore as a heartbeat datastore, please mount the target datastore to two or more ESXi hosts in the cluster.
You can check the mount status of the datastore by following the KB How to check datastore mount status.