VMware vCenter Server 8.0.x
VMware vCenter Server 7.0.x
# openssl s_client -connect destination-ip:ssl-portnc -zv <vCenter_ip> 443
Running "openssl s_client -connect "remote vCenter fqdn":443" from a vCenter with the problem does not retrieve the certificates, but does grab certs from a working vCenter to the content library: