Is it possible to add the hostname/computer name to the subject line of an alert for unapproved file blocks?
Hostname is only available for the Elevated Privilege alerts.
Depending on the user case, an option may be to utilize a custom link in the notifier for unapproved blocks. This will used the mail client set in the OS to send an email to your IT department. Here's an example:
mailto:support@mydomain.com?subject=Blocked File <TargetName>&body=<UserName> on <DomainName>\<ComputerName>has reported block of <TargetName>.%0AFile details available at https://myappcserver.local/file-details.php?hash=<TargetSha256> <FriendlyText:Please click here to notify IT.>Elevated Privilege: A computer remains in local approval mode longer than a specified time period. The default is one hour, but can be modified. No computer should remain in approval mode longer than is necessary to install software.