This articles explains the steps to update/change the vCenter Server Appliance (VCSA) Hostname/PNID using vCenter Server Appliance Management Interface (VAMI)
VMware vCenter Server 8.0
Note : Ensure a backup/snapshot of the vCenter Server is taken before proceeding with the following steps. For vCenter in ELM refer Snapshot Best practices for vCenter Server Virtual Machines
Networking and click Edit on the Network Settings.NIC 0 (Management Network), and click Next.Hostname and DNS section. SSO administrator credentials for vCenter Server Appliance.