VMware Cloud Foundation 9.x
This is an expected behavior provided that the Identity broker is already setup in Embedded Deployment Mode.
For a single vCenter Server/VCF instance, only a single mode of Identity Broker can be deployed. It can either be Embedded Deployment Mode or Appliance Deployment Mode. If the Embedded mode is already enabled on the vCenter/VCF instance, that vCenter/VCF instance won't show up under "Select vCenter server" drop down menu when configuring a new VCF Identity broker.
To setup the VCF Identity Broker in Appliance mode, the Embedded Deployment Mode configuration will have to be removed. To do the same,