When enabling the MI210 graphics card for SR-IOV it doesn't allow for the VF devices to be configured for passthrough.
ESXi - /var/run/log/vmkernel.log:
2025-07-17T16:34:06.620Z In(182) vmkernel: cpu0:2097889)gim error libgv: [0:e5:0:0][mi200_fw_compatibility_check:55] Version Compatibility Error: FW 0x7 Ver = 0x8045. Sec Ver = 0xd2040322025-07-17T16:34:06.620Z In(182) vmkernel: cpu0:2097889)gim error libgv: [0:e5:0:0][PF][psp_v13_hw_init:987] Failed to load FW 02025-07-17T16:34:06.620Z In(182) vmkernel: cpu0:2097889)gim info libgv: [0:e5:0:0][amdgv_error_dump_stack:740] put event AMDGV_ERROR_FW_UCODE_LOAD_FAIL, error code: 0x800090052025-07-17T16:34:06.620Z In(182) vmkernel: cpu0:2097889)gim info libgv: [amdgv_print_failed_init_name:1307] failed to hw_init of mi200_psp_func2025-07-17T16:34:06.620Z In(182) vmkernel: cpu0:2097889)gim error libgv: [0:e5:0:0][PF][amdgv_device_func_hw_init:1643] Failed to HW init.
ESXi 7.0
ESXi 8.0
Follow the process outlined by AMD for the enablement. If after stepping through the processes the VF devices still aren't being enabled please check the logging on the host.
Update the firmware of the card based on hardware vendor recommendations.