VMware Site Recovery Manager 8.x
The issue happen because the appliance couldn't translate the vCenter FQDN into an IP address because of the DNS issues.
Check the DNS configuration on the appliance and fix the configuration. After that, execute a ping from the appliance to verify connectivity with the vCenter using its FQDN.
Please check Configure the Site Recovery Manager Appliance Network Settings for customizing/checking the network settings, including DNS.
Once the configuration is corrected and the ping test passes, the configuration of the Site Recovery Manager Appliance should succeed.
If the issue persists even after resolving the DNS configuration, please contact Broadcom Support.