VMware vCenter Server 7.0.x
VMware vCenter Server 8.0.x
1. Verify the vCenter DNS settings and ping the ESXi FQDN from vCenter as outlined in the KB article: Resolving ESXi Host Disconnects Caused by DNS Resolution Failures in vCenter Server
2. If the ping fails, resolve the DNS issue or add entries for the ESXi hosts in the /etc/hosts file.
e.g. <ESXi_IP_ADDRESS> <ESXi_FQDN>
3. Verify connectivity from vCenter to the ESXi hosts' TCP port 902. If it is not open, check the ESXi/vCenter firewall settings and involve the network team to investigate any firewall issues.
nc -zv <ESXi_FQDN> 902