Customer can not customize a guest VM to have IPv6 only network configuration.
VMware vCenter Server 7.x.x
VMware vCenter Server 8.x.x
CustomizationIPSettings. Reference: vSphere Web Services APICustomizationIpGenerator) property is mandatory, this property is extended by CustomizationCustomIpGenerator, CustomizationDhcpIpGenerator, CustomizationFixedIp, CustomizationUnknownIpGenerator, each of them represents a way of customizing an IPv4 address to guest vm.CustomizationIPSettingsIpV6AddressSpec) property is optional, this property represents the way of customizing an IPv6 address to guest vm.N/A