After adding and configuring the 1st iSCSI adapter the option to add another is greyed out.
vSphere - vCenter and ESXi
Only a single software iSCSI adapter is supported and able to be configured.
If multiple paths and/or subnets are required while using a software iSCSI adapter, multiple vmkernel ports with access to the needed networks may be configured and attached to the iSCSI adapter.
Note that multiple hardware iSCSI adapters may be used.
Further information on configuring iSCSI is available in the attached best practice resources document, and in KB 317719 outlining considerations when using iSCSI software port binding.