This article explains the issue in vSAN cluster where ESXi host will take very long time to enter the Maintenance Mode ( Default Mode - Ensure Accessibility )
VMware ESXi (All Versions)
By default the Maintenance Mode is set with "Ensure Accessibility" which will ensure all the vSAN objects will be migrated to other hosts within the cluster only after which the Maintenance Mode operation will be marked as completed.
Note : A detailed overview of the VM Storage Policies is provided in an article vSAN Policies ( refer section - Storage Policy - Availability )