When attempting to put a vSAN Host in Maintenance Mode you will see the error:
"Failed to enter maintenance mode due to one or more candidate objects for migration being currently inaccessible"
The error occurs because inaccessible vSAN Object(s) exist in the vSAN Cluster (where the affected Host is a member of).
Investigate the existing inaccessible Objects by reviewing this KB Dealing with inaccessible objects in a vSAN cluster.
If assistance is required, please open a Ticket with VMware by Broadcom Support.