When trying to remove a host using the Add / Manage hosts function of vCenter --> Networking --> ZZZZZ, you receive a failed like the following in the Task Console of vCenter:
This occurs when at some point in the past, the host had been added to an NSX Transport zone.
vCenter
ESXi
Even though the host may no longer have any active dvPortgroups associated with its membership in the vDS, this message indicates that at some point in the past, the host was added to an NSX Transport zone.
Please follow the process described in Troubleshooting VMware NSX Uninstall Process
After NSX has been removed from the host, repeat the attempt to remove the host using the Add / Manage hosts function of vCenter --> Networking --> ZZZZZ (where ZZZZZ is the name of the vDS)