Non-zero values are being shown for exclusive buffer waits on Performance Monitor's online screens and batch reports (PMIRPT21, PMIRPT22 and PMIRPT23).
Release: All supported releases.
These are an indication of contention by multiple transactions for update access to the same database page.
There is a good technical description of the various types of buffer waits at 89-08-1171 WHAT DOES A 'BUFFER WAIT' MEAN?. This is an old document but it describes internal technical information which is still correct.
The most common things to look for are:
Note that this is generally not something that can be addressed by simply adding pages to the buffer.