1. Remove the Computer account from AD corresponding to the vCenter hostname.
2. Execute the below commands from an SSH session to the vCenter Server Appliance.
/opt/likewise/bin/domainjoin-cli leave
rm -f /etc/krb5.conf
rm -f /etc/krb5.keytab
/opt/likewise/bin/domainjoin-cli join <Domain_Name> <user_name>
3. Sign out and log back into the Windows machine from where you are trying to connect to vCenter via PowerCLI.
4. Connect to the vCenter via PowerCLI once logged in.