The VMkernel routes physical mode SCSI commands directly over the RDM mapping without any modifications. The RDM vmdk pointer file must reside on a VMFS location, therefore the operation fails because the NFS protocol does not support SCSI commands over this interface.
When adding an RDM to a virtual machine hosted on an NFS datastore, the Store with Virtual Machine option is grayed out in the Add Raw Device Mapping wizard. Select a specific VMFS Datastore from the available list for the location of the pointer file instead.
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