vCenter Server 4.1 and 5.x are supported only on 64bit operating systems. You cannot install or upgrade vCenter Server 4.1 or 5.x on 32bit operating systems.
To resolve this issue, ensure to install vCenter Server 4.1 or 5.x on a supported 64bit operating system.
For a list of supported 64bit operating systems in vCenter Server 4.1, see
Operating System Compatibility in the
vSphere Compatibility Martix
For vCenter Server 5.x, see: