vCenter 4.x and 5.0 service fails to start after changing the FQDN/hostname.
VMware does not support changing hostname for vCenter Server. If the vCenter Server name has changed refer one of the following steps to fix the issue.
<C:\Documents and Settings\All Users\Application Data\VMware\VMware VirtualCenter\SSL>
<C:\Documents and Settings\All Users\Application Data\VMware\Infrastructure\Inventory>
<C:\Program Data\VMware\VMware VirtualCenter\SSL>
<C:\Program Files\VMware\Infrastructure\Inventory Service\SSL>