Run this command:
esxcli network nic list
The output should come up similar to:
Name PCI Device Driver Admin Status Link Status Speed Duplex MAC Address MTU Description
------- ------------ ------ ------------ ----------- ------ ------ ----------------- ---- -----------
vmnic0 0000:01:00.0 ixgben Up Up 1000 Full ec:f4:bb:##:##:## 1500 Intel(R) Ethernet Controller X540-AT2
vmnic1 0000:01:00.1 ixgben Up Up 1000 Full ec:f4:bb:##:##:## 1500 Intel(R) Ethernet Controller X540-AT2
Note: The Admin Status is the only portion of the output that ESXi controls. The link status column specifies the status of the link between the physical network adapter and the physical switch. The link status can be either Up or Down.
Note: Only cards running auto-negotiation/10Mb/100Mb/1000Mb/10000Mb speeds are supported.