This article provides information on setting up the correct NIC teaming policies to allow iSCSI port binding.
Port binding is used in iSCSI when multiple VMkernel ports for iSCSI reside in the same broadcast domain and IP subnet to allow multiple paths to an iSCSI array that broadcasts a single IP address..
Port binding is required for iSCSI vmkernels when they are in the same subnet.
Note: Since the ESXi host receives a routing table entry automatically for each vmkernel on the host, it is not recommended to override the default gateway on the vmkernel unless layer 3 connectivity is required.
Symptoms: