This issue is resolved in:
- VMware vCenter Server 6.0 Update 3c
- VMware vCenter Server 6.5 Update 1d.
Workaround:
Remove and re-add the Identity Source with correct URLs
- Login to Webclient
- Click on Home -> Administration
- Click on Configuration -> Identity Sources
- Select Identity Source and Click on Delete button
- Recreate the Identity Source with the correct LDAP Server information, follow VMware Doc Article in Related Information