Symptoms:
Given is a Cluster with at least two hosts (host-a and host-b) with two different CPU Generation; in this case Sandy Bridge and Haswell.
The vCenter is running on host-b which has the older generation CPU host-a.
VMware vCenter Server Appliance 6.0.x
VMware vCenter Server Appliance 7.0.x
To enable the EVC Mode on this cluster follow the following steps.
host-bhost-b from the Inventory of the vCenterhost-b to the new clusterhost-a.host-a using either the Host-UI or the vSphere Clienthost-ahost-b using either the Host-UI or the vSphere Clienthost-bhost-bhost-a from the old clusterhost-a to the new cluster and power-on all VMs