vCenter Services in vCenter Server 6.5/6.7 are controlled by vmon service. If the windows vCenter service account need to be changed for a particular service it need to be updated through vmon.
The KB explain on how to change vCenter Server Service account in vCenter Server 6.5/6.7
Windows Administrative Tools -> Local Security -> Local Policies -> User Rights Management'( A reboot is required for change to take effect).cd C:\Program Files\VMware\vCenter Server\binservice-control --stop --allservice-control --start vmware-vmon vmon.exe -P username@domainvmon-cli.exe -lvmon-cli.exe -U cis-license --runasuser username@domainvmon-cli.exe -U cm --runasuser username@domainvmon-cli.exe -U content-library --runasuser username@domainvmon-cli.exe -U eam --runasuser username@domainvmon-cli.exe -U imagebuilder --runasuser username@domainvmon-cli.exe -U mbcs --runasuser username@domainvmon-cli.exe -U netdumper --runasuser username@domainvmon-cli.exe -U perfcharts --runasuser username@domainvmon-cli.exe -U rbd --runasuser username@domainvmon-cli.exe -U rhttpproxy --runasuser username@domainvmon-cli.exe -U sca --runasuser username@domainvmon-cli.exe -U sps --runasuser username@domainvmon-cli.exe -U vapi-endpoint --runasuser username@domainvmon-cli.exe -U vmcam --runasuser username@domainvmon-cli.exe -U vmonapi --runasuser username@domainvmon-cli.exe -U vmsyslogcollector --runasuser username@domainvmon-cli.exe -U vpxd --runasuser username@domainvmon-cli.exe -U vpxd-svcs --runasuser username@domainvmon-cli.exe -U vsan-health --runasuser username@domainvmon-cli.exe -U vsm --runasuser username@domainvmon-cli.exe -U vsphere-client --runasuser username@domainvmon-cli.exe -U vsphere-ui --runasuser username@domain