This is an expected behavior because, unlike the USB controllers, the virtual machine does not own the USB device. The USB device can be used by other virtual machines for back up purposes, whereas other virtual machines cannot use the same USB controller.
This issue is resolved in ESXi 5.5. In ESXi 5.5, the attached USB device is ignored during export. A warning is generated, but the OVF export continues.
To resolve this issue in earlier releases, edit the virtual machine settings and disconnect the USB device.