The only one that both AWS and the broker are happy with is changing the subnet group to force AWS to certain AZs in a MultiAZ scenario.
The broker only supports changing the DB Subnet group for the whole RDS service offerings group. Through the tile, customer would have to go to RDS Config and in Networking Select Custom VPC and then choose the DB Subnet Group Name. You will need to create in the AWS console a subnet group that matches your requirements: same VPC that your current one but just choosing a subset of subnets belonging to the AZs you want instances to be created in. Save and apply changes.

This would only affect newly created instances as there are no update operations available through the broker. Existing instances won’t be affected. However it will affect all your RDS offerings.