To configure this, it only requires add multiple LDAP server name or IP address into the ldapserver setting, separted by space, like below:
host all all 0.0.0.0/0 ldap ldapserver="192.168.31.245 192.168.31.44" ldapport=389 ldapprefix="uid=" ldapsuffix=",ou=tanzu,dc=vc,dc=loca"
Once changed, gpstop -u to reload the parameter.