Starting from VMWare Postgres 13.4, the location of all binary files has moved from /usr to /opt/vmware/postgres/13
If we are trying to upgrade the VMware Postgres from a version prior to 13.4 to 13.4 afterward, then some extra steps need to be performed to make sure the new cluster is loading the correct binary.
VMware has published the document with all the steps, please refer to this link for more details. Link: Upgrading VMware Postgres