This article discusses the options available to reduce the number of segments in a GPDB cluster.
There is no option to remove a segment in GPDB while it is online. The recommended ways to reduce the number of segments in a cluster are:
The gpcopy utility can be used to migrate data to a new cluster with a different number of segments. See Migrating Data with gpcopy
The data can be backed up using the gpbackup/gprestore utilities and restored to the the new cluster or reinitialised cluster with "--resize-cluster" option.