Software Policy created on the Enterprise Service (ES) was not sealed at the moment it was created and, after it's sealed, is not being replicated down to the Domain Manager (DM).
Client Automation 14.x
When a Software Policy is created on the ES, there is a checkbox called "Seal and distribute Software Policy":
If this is not clicked, the Policy gets created, but no replicated down to the DM at that time, but if the policy gets sealed after this, the policy won't be replicated until a new Software Deployment Job is set.
In order to create a new Software Deployment Job of this recently sealed policy, right-click on the policy and select "Software Deployment Job based on..."
On the Wizard, select the target DM and also place a name for the Container:
Once this is done, a new job will be Software Distribution job will be created on the ES, and also a new Software Job will be created on the DM: