Salesforce senders are stopped or tagged by the Email Impersonation Control service.
Email Security.cloud
Salesforce does not use the domain Salesforce.com solely when sending emails, but rather a long string ID followed by the domain Salesforce.com. This string changes per user, whitelisting each single user becomes a challenging task.
Use the wildcard *.salesforce.com to whitelist the sending domain.
Caution: Exercise care when using wildcards for any approved senders, as they can broaden security exposure.