Salesforce senders are stopped or tagged by the Email Impersonation Control service.
Salesforce does not use the domain Salesforce.com solely when sending emails, but rather a long string ID followed by the domain Salesforce.com. This string changes per user, whitelisting each single user becomes a challenging task.
Broadcom recommends to use wildcard for whitelisting the sending domain:
*.salesforce.com
Please use caution when utilizing wildcards for any Approved senders.