If your iOS device requires an on-demand VPN to connect to your internal network, Symantec Mobile Encryption for iOS will not cause the VPN to start when it tries to connect to your Encryption Management Server.
Please note that Mobile Encryption for iOS reaches EOS (End of Service) on 31 December 2020 and EOL (End of Life) on 31 March 2021.
Mobile Encryption for iOS is designed to communicate with Encryption Management Server using a fully qualified domain name (FQDN) using standard DNS functionality. Mobile Encryption for iOS was not designed to use on-demand VPN connections.
Symantec Mobile Encryption for iOS resolves DNS names by doing a DNS lookup using cross-platform POSIX calls. This method does not trigger the on-demand VPN.